Abstract
The IR carbonyl stretching frequencies of [Fe2(SRS)(CO)6] complexes correlate well with their first reduction potential; an [FeFe] hydrogenase model with a very mild reduction potential has been realized by using a strongly electron deficient carborane-dithiolate bridge.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Binding Sites
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Boron Compounds / chemistry*
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Boron Compounds / metabolism*
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Crystallography, X-Ray
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Electrons*
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Hydrogenase / chemistry*
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Hydrogenase / metabolism*
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Iron-Sulfur Proteins / chemistry*
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Iron-Sulfur Proteins / metabolism*
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Models, Molecular*
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Protein Structure, Tertiary
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Spectrophotometry, Infrared
Substances
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Boron Compounds
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Iron-Sulfur Proteins
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iron hydrogenase
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Hydrogenase