Gas-liquid selective oxidations with oxygen under explosive conditions in a micro-structured reactor

Lab Chip. 2008 May;8(5):814-7. doi: 10.1039/b717985e. Epub 2008 Mar 26.

Abstract

The gas-liquid oxidation of cyclohexane is performed at high temperature (>200 degrees C) and pressure (up to 25 bar) using pure oxygen in a Pyrex capped silicon etched microreactor which allows convenient screen reaction conditions well above the flammability limit.

MeSH terms

  • Cyclohexanes / chemistry*
  • Explosive Agents / chemistry*
  • Gases / chemistry
  • Ligands
  • Microfluidic Analytical Techniques / instrumentation*
  • Microfluidic Analytical Techniques / methods*
  • Molecular Structure
  • Oxidation-Reduction
  • Oxygen / chemistry*
  • Particle Size
  • Pressure
  • Sensitivity and Specificity
  • Silicon / chemistry
  • Temperature

Substances

  • Cyclohexanes
  • Explosive Agents
  • Gases
  • Ligands
  • Cyclohexane
  • Oxygen
  • Silicon