Azide monoliths as convenient flow reactors for efficient Curtius rearrangement reactions

Org Biomol Chem. 2008 May 7;6(9):1587-93. doi: 10.1039/b801634h. Epub 2008 Mar 12.

Abstract

The preparation and use of an azide-containing monolithic reactor is described for use in a flow chemistry device and in particular for conducting Curtius rearrangement reactions via acid chloride inputs.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Azides / chemistry*
  • Carbamates / chemical synthesis*
  • Carbamates / chemistry
  • Chromatography, High Pressure Liquid / instrumentation*
  • Chromatography, High Pressure Liquid / methods*
  • Equipment Design
  • Ion Exchange Resins / chemistry
  • Mass Spectrometry / instrumentation
  • Mass Spectrometry / methods
  • Molecular Structure
  • Particle Size
  • Porosity
  • Quaternary Ammonium Compounds / chemistry
  • Sensitivity and Specificity
  • Surface Properties
  • Urea / analogs & derivatives
  • Urea / chemical synthesis*
  • Urea / chemistry

Substances

  • Azides
  • Carbamates
  • Ion Exchange Resins
  • Quaternary Ammonium Compounds
  • Urea