Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand

Ya-Qian Lan; Shun-Li Li; Zhong-Min Su; Kui-Zhan Shao; Jian-Fang Ma; Xin-Long Wang; En-Bo Wang

doi:10.1039/b714413j

Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand

Chem Commun (Camb). 2008 Jan 7:(1):58-60. doi: 10.1039/b714413j.

Authors

Ya-Qian Lan¹, Shun-Li Li, Zhong-Min Su, Kui-Zhan Shao, Jian-Fang Ma, Xin-Long Wang, En-Bo Wang

Affiliation

¹ Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China.

PMID: 18399405
DOI: 10.1039/b714413j

Abstract

Two enantiomerically 3D chiral POM-based architectures have been constructed based on the achiral ligand bbi, [V10O26](4-) polyoxoanion and mixed valence Cu(I/II) without a chiral auxiliary, and they represent the first examples of enantiomerically 3D POM-based compounds using achiral ligands.