Comment on "equilibrium polymerization and gas-liquid critical behavior in the Stockmayer fluid"

Phys Rev E Stat Nonlin Soft Matter Phys. 2008 Jan;77(1 Pt 1):013501; discussion 013502. doi: 10.1103/PhysRevE.77.013501. Epub 2008 Jan 4.

Abstract

In a recent paper [Phys. Rev. E 75, 011506 (2007)] Hentschke presented new results on the vapor-liquid transition in the Stockmayer fluid. In this Comment, we analyze the data further and demonstrate that at high dipole strength, the isotropic attractive part of the Stockmayer potential is negligible compared to the thermal energy at the vapor-liquid critical point. The results therefore suggest that the transition is largely driven by the dipolar interactions.

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