Enhanced photosusceptibility near Tc for the light-induced insulator-to-metal phase transition in vanadium dioxide

Phys Rev Lett. 2007 Nov 30;99(22):226401. doi: 10.1103/PhysRevLett.99.226401. Epub 2007 Nov 30.

Abstract

We use optical-pump terahertz-probe spectroscopy to investigate the near-threshold behavior of the photoinduced insulator-to-metal (IM) transition in vanadium dioxide thin films. Upon approaching Tc a reduction in the fluence required to drive the IM transition is observed, consistent with a softening of the insulating state due to an increasing metallic volume fraction (below the percolation limit). This phase coexistence facilitates the growth of a homogeneous metallic conducting phase following superheating via photoexcitation. A simple dynamic model using Bruggeman effective medium theory describes the observed initial condition sensitivity.