Synthesis of functionalized furans via gold(I)-catalyzed Claisen-type rearrangement

J Org Chem. 2008 Jan 18;73(2):730-3. doi: 10.1021/jo7022685. Epub 2007 Dec 13.

Abstract

Gold(I)-catalyzed cyclization of pentenynyl allyl ethers allows the rapid construction of functionalized furans. The concerted oxy-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers.

Publication types

  • Retracted Publication

MeSH terms

  • Catalysis
  • Cyclization
  • Ethers / chemistry
  • Furans / chemical synthesis*
  • Furans / chemistry
  • Gold / chemistry*
  • Molecular Structure
  • Stereoisomerism

Substances

  • Ethers
  • Furans
  • Gold