Syntheses of calix[4]pyrroles by amberlyst-15 catalyzed cyclocondensations of pyrrole with selected ketones

Molecules. 2007 Nov 9;12(11):2458-66. doi: 10.3390/12112458.

Abstract

A facile and efficient protocol is reported for the synthesis of calix[4]pyrroles and N-confused calix[4]pyrroles in moderate to excellent yields by reaction of dialkyl or cycloalkyl ketones with pyrrole catalyzed by reusable Amberlyst(TM)-15 under eco-friendly conditions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acids / chemistry*
  • Calixarenes / chemical synthesis*
  • Calixarenes / chemistry
  • Ketones / chemistry*
  • Molecular Structure
  • Porphyrins / chemical synthesis*
  • Porphyrins / chemistry
  • Pyrroles / chemistry*
  • Styrenes / chemistry*

Substances

  • Acids
  • Ketones
  • Porphyrins
  • Pyrroles
  • Styrenes
  • amberlyst-15
  • calix(4)pyrrole
  • Calixarenes