Manganese and iron flavonolates as flavonol 2,4-dioxygenase mimics

Chem Commun (Camb). 2007 Dec 28:(48):5235-7. doi: 10.1039/b711864c. Epub 2007 Oct 11.

Abstract

Mononuclear manganese(II) and iron(III) flavonolates were synthesized as synthetic enzyme-substrate complexes, and their oxygenation reactions as biomimetic functional models with relevance to flavonol 2,4-dioxygenases are briefly described.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Crystallography, X-Ray
  • Dioxygenases / chemistry*
  • Flavonoids / chemistry*
  • Iron / chemistry*
  • Kinetics
  • Manganese / chemistry*
  • Models, Biological
  • Models, Molecular
  • Molecular Mimicry
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry

Substances

  • Flavonoids
  • Organometallic Compounds
  • Manganese
  • Iron
  • Dioxygenases
  • flavonol 2,4-dioxygenase