Bowl-shaped Cu(I) metallamacrocyclic ethylene and carbonyl adducts as structural analogues of organic calixarenes

Masahiko Maekawa; Hisashi Konaka; Toshie Minematsu; Takayoshi Kuroda-Sowa; Megumu Munakata; Susumu Kitagawa

doi:10.1039/b713618h

Bowl-shaped Cu(I) metallamacrocyclic ethylene and carbonyl adducts as structural analogues of organic calixarenes

Chem Commun (Camb). 2007 Dec 28:(48):5179-81. doi: 10.1039/b713618h. Epub 2007 Oct 16.

Authors

Masahiko Maekawa¹, Hisashi Konaka, Toshie Minematsu, Takayoshi Kuroda-Sowa, Megumu Munakata, Susumu Kitagawa

Affiliation

¹ Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan. maekawa@rist.kindai.ac.jp

PMID: 18060134
DOI: 10.1039/b713618h

Abstract

Three novel Cu(I) metallacalixarenes with C(2)H(4) and CO legs, in which an anion is accommodated in the inside cavity, were self-assembled by anion templation and have been structurally characterized.

MeSH terms

Calixarenes / chemistry*
Carbon Monoxide / chemistry*
Copper / chemistry*
Crystallography, X-Ray
Ethylenes / chemistry*
Macrocyclic Compounds / chemistry*
Magnetic Resonance Spectroscopy / methods
Magnetic Resonance Spectroscopy / standards
Models, Molecular
Molecular Structure
Organometallic Compounds / chemistry*
Reference Standards

Substances

Ethylenes
Macrocyclic Compounds
Organometallic Compounds
Calixarenes
Copper
Carbon Monoxide