(Nitrato-kappaO)bis(pyridine-2-carboxamide-kappa2N1,O)mercury(II) nitrate

Acta Crystallogr C. 2007 Dec;63(Pt 12):m557-9. doi: 10.1107/S0108270107051566. Epub 2007 Nov 14.

Abstract

In the title compound, [Hg(NO3)(C6H6N2O)2]NO3, the Hg(II) atom is five-coordinate. The distorted square-pyramidal mercury(II) coordination environment is achieved by two N,O-bidentate picolinamide ligands, with one O-monodentate nitrate ion in the apical position. A seven-coordinate extended coordination environment is completed by two additional weak Hg...O interactions, one from the coordinated nitrate ion and one from the other nitrate ion, to give seven-coordination. The molecules are linked into a two-dimensional network by N-H...O hydrogen bonds.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Ligands
  • Mercury Compounds / chemistry*
  • Models, Molecular
  • Molecular Structure
  • Nitrates / chemistry*
  • Organomercury Compounds / chemical synthesis*
  • Organomercury Compounds / chemistry*
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry*

Substances

  • (nitrato-kappaO)bis(pyridine-2-carboxamide-kappa2N1,O)mercury(II)
  • Ligands
  • Mercury Compounds
  • Nitrates
  • Organomercury Compounds
  • Organometallic Compounds
  • mercury nitrate