1,1,1,1,4,4,4,4-Octacarbonyl-2,2,3,3,5,5,6,6-octamethyl-cyclo-2,3,5,6-tetraantimony-1,4-dichromium

Hans Joachim Breunig; Enno Lork; Ovidiu Moldovan; Ciprian I Raţ

doi:10.1107/S0108270107049943

1,1,1,1,4,4,4,4-Octacarbonyl-2,2,3,3,5,5,6,6-octamethyl-cyclo-2,3,5,6-tetraantimony-1,4-dichromium

Acta Crystallogr C. 2007 Dec;63(Pt 12):m548-9. doi: 10.1107/S0108270107049943. Epub 2007 Nov 14.

Authors

Hans Joachim Breunig¹, Enno Lork, Ovidiu Moldovan, Ciprian I Raţ

Affiliation

¹ Universität Bremen, Leobener Strasse NW2, 28334 Bremen, Germany. breunig@chemie.uni-bremen.de

PMID: 18057590
DOI: 10.1107/S0108270107049943

Abstract

The structure of the title compound, alternatively called bis(mu-tetramethyldistibinediyl)bis(tetracarbonylchromium), [Cr2Sb4(CH3)8(CO)8], consists of two Me4Sb2 bridging units between Cr(CO)4 complex fragments. The centre of the molecule is located on a special position of 2/m symmetry. This is the first characterized Sb4Cr2 heterocycle.