Total synthesis of (+)-komarovispirone

Org Lett. 2008 Jan 3;10(1):89-91. doi: 10.1021/ol7017449. Epub 2007 Dec 4.

Authors

George Majetich¹, Jianhua Yu

Affiliation

¹ Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA. majetich@chem.uga.edu

PMID: 18052177
DOI: 10.1021/ol7017449

Abstract

(+)-Komaroviquinone photolytically rearranges to (+)-komarovispirone. A rationalization of this isomerization is presented.

Publication types

Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Diterpenes / chemical synthesis*
Diterpenes / chemistry
Molecular Structure
Quinones / chemical synthesis*
Quinones / chemistry
Stereoisomerism

Substances

Diterpenes
Quinones
komaroviquinone