Synthesis of cyclophellitol utilizing a palladium chloride mediated-Ferrier-II rearrangement

Hideyo Takahashi; Shiro Ikegami

doi:10.3390/10080901

Synthesis of cyclophellitol utilizing a palladium chloride mediated-Ferrier-II rearrangement

Molecules. 2005 Aug 31;10(8):901-11. doi: 10.3390/10080901.

Authors

Hideyo Takahashi¹, Shiro Ikegami

Affiliation

¹ Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa 199-0195, Japan.

Abstract

Cyclophellitol and its C3-epimer have been synthesized from5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeletonwas constructed through a Ferrier-II reaction meditated by PdCl2.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Cyclohexanols / chemical synthesis*
Cyclohexanols / chemistry
Models, Chemical
Molecular Conformation
Palladium / chemistry*
Temperature

Substances

Cyclohexanols
cyclophellitol
Palladium
palladium chloride