Optically sensed, molecular shuttles driven by acid-base chemistry

Chem Commun (Camb). 2007 Dec 7:(45):4752-4. doi: 10.1039/b710708k. Epub 2007 Sep 10.

Abstract

A pair of bistable [2]rotaxane, molecular shuttles were prepared that combine 1,2-bis(pyridinium)ethane and benzylanilinium recognition sites; acid-base controlled shuttling of DB24C8 was accompanied by a change in colour and/or fluorescence intensity.