Abstract
A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alcohols / chemistry
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Alkanes / chemistry
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Alkenes / chemistry
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Catalysis
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Iodobenzenes / chemistry
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Ketones / chemical synthesis
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Ketones / chemistry
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Magnetic Resonance Spectroscopy / methods
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Manganese / chemistry*
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Oxidation-Reduction
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Oxygen / chemistry*
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Peracetic Acid / chemistry
Substances
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Alcohols
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Alkanes
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Alkenes
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Iodobenzenes
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Ketones
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Organometallic Compounds
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Manganese
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Peracetic Acid
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Oxygen