Conversion of a porous material based on a Mn(II)-TCNQF(4) honeycomb net to a molecular magnet upon desolvation

Chem Commun (Camb). 2007 Nov 28:(44):4611-3. doi: 10.1039/b710149j. Epub 2007 Oct 2.

Abstract

Removal of methanol molecules from the interstices of a metal-organic framework based on a 2-D hexagonal Mn(II)-TCNQF(4) net results in stronger magnetic interactions and leads to a glassy magnetically ordered state; the magnetic behavior can be reversibly cycled upon solvation-desolvation of the material.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Magnetics
  • Manganese / chemistry*
  • Models, Molecular
  • Molecular Structure
  • Nitriles / chemistry*
  • Organometallic Compounds / chemistry*
  • Porosity
  • Solubility
  • Temperature

Substances

  • Nitriles
  • Organometallic Compounds
  • tetracyanoquinodimethane
  • Manganese