Abstract
Removal of methanol molecules from the interstices of a metal-organic framework based on a 2-D hexagonal Mn(II)-TCNQF(4) net results in stronger magnetic interactions and leads to a glassy magnetically ordered state; the magnetic behavior can be reversibly cycled upon solvation-desolvation of the material.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Crystallography, X-Ray
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Magnetics
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Manganese / chemistry*
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Models, Molecular
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Molecular Structure
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Nitriles / chemistry*
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Organometallic Compounds / chemistry*
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Porosity
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Solubility
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Temperature
Substances
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Nitriles
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Organometallic Compounds
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tetracyanoquinodimethane
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Manganese