A new cyclic borazine species B(8)(NH)(4)(NMe(2))(8) containing a twelve-membered B(8)N(4) ring

George Bramham; Jonathan P H Charmant; Alistair J R Cook; Nicholas C Norman; Christopher A Russell; Saowanit Saithong

doi:10.1039/b711487g

A new cyclic borazine species B(8)(NH)(4)(NMe(2))(8) containing a twelve-membered B(8)N(4) ring

Chem Commun (Camb). 2007 Nov 28:(44):4605-7. doi: 10.1039/b711487g. Epub 2007 Sep 27.

Authors

George Bramham¹, Jonathan P H Charmant, Alistair J R Cook, Nicholas C Norman, Christopher A Russell, Saowanit Saithong

Affiliation

¹ University of Bristol, School of Chemistry, Bristol, UK.

PMID: 17989806
DOI: 10.1039/b711487g

Abstract

The reaction between B(2)(NMe(2))(4) and two equivalents of [NH(4)][PF(6)] in thf at room temperature affords the new cyclic borazine B(8)(NH)(4)(NMe(2))(8) containing a non-planar twelve-membered ring with alternating B(2)(NMe(2))(2) and NH units.