[Bis(3,5-dimethylpyrazol-1-yl-kappaN2)dithioacetato-kappaS](triphenylphosphine-kappaP)copper(I)

Acta Crystallogr C. 2007 Nov;63(Pt 11):m513-5. doi: 10.1107/S0108270107046665. Epub 2007 Oct 13.

Abstract

In the title compound, [Cu(C(12)H(15)N(4)S(2))(C(18)H(15)P)], the copper(I) center is tetrahedrally coordinated by one S atom and two N atoms from one bis(3,5-dimethylpyrazol-1-yl)dithioacetate ligand and one P atom from a triphenylphosphine ligand. In the crystal structure, adjacent pyrazole rings are involved in weak pi-pi interactions, thereby forming a one-dimensional zigzag chain running along the b axis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Copper / chemistry*
  • Molecular Structure
  • Organometallic Compounds / chemistry*

Substances

  • (bis(3,5-dimethylpyrazol-1-yl-kappaN2)dithioacetato-kappaS)(triphenylphosphine-kappaP)copper(I)
  • Organometallic Compounds
  • Copper