trans-Bis(azido-kappaN)bis(pyridine-2-carboxamide-kappa2N1,O2)nickel(II)

Acta Crystallogr C. 2007 Nov;63(Pt 11):m507-9. doi: 10.1107/S0108270107047312. Epub 2007 Oct 13.

Abstract

In the title compound, [Ni(N(3))(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom lies on an inversion centre. The distorted octahedral nickel(II) coordination environment contains two planar trans-related N,O-chelating picolinamide ligands in one plane and two monodentate azide ligands perpendicular to this plane. Molecules are linked into a three-dimensional framework by N-H...N hydrogen bonds.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrogen Bonding
  • Molecular Conformation
  • Nickel / chemistry*
  • Organometallic Compounds / chemistry*

Substances

  • Organometallic Compounds
  • bis(azido-kappaN)bis(pyridine-2-carboxamide-kappa2N1,O2)nickel(II)
  • Nickel