Bis[N-(4-nitrophenyl)thiobenzamidato]mercury(II)

Acta Crystallogr C. 2007 Nov;63(Pt 11):m494-5. doi: 10.1107/S010827010704694X. Epub 2007 Oct 13.

Abstract

The molecule of the title compound, [Hg(C(13)H(9)N(2)O(2)S)(2)], has approximate twofold rotation symmetry, with the Hg atom in an essentially linear two-coordinate HgS(2) environment supported by secondary pi interactions with the nitrophenyl rings of both ligands. The ligands are in the imine-thiolate rather than the amine-thione tautomeric form.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Molecular Structure
  • Organomercury Compounds / chemistry*

Substances

  • Organomercury Compounds
  • bis(N-(4-nitrophenyl)thiobenzamidato)mercury(II)