Critical Casimir effect in superfluid wetting films

Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Sep;76(3 Pt 1):031124. doi: 10.1103/PhysRevE.76.031124. Epub 2007 Sep 19.

Abstract

Recent experimental data for the complete wetting behavior of pure 4He and of 3He-4He mixtures exposed to solid substrates show that there is a change of the corresponding film thicknesses L upon approaching thermodynamically the lambda transition and the tricritical end point, respectively, which can be attributed to critical Casimir forces fC. We calculate the scaling functions theta of fC within models representing the corresponding universality classes. For the mixtures our analysis provides an understanding of the rich behavior of theta deduced from the experimental data and predicts the crossover behavior between the tricritical point and the lambda transition of pure 4He which are connected by a line of critical points. The formation of a "soft-mode" phase within the wetting films gives rise to a pronounced maximum of fC below the tricritical point as observed experimentally. Near the tricritical point we find logarithmic corrections approximately L(-3)(ln L)1/2 for the leading behavior of theta dominating the contributions from the background dispersion forces.