Hydrogen-bonded sheets of R2(2)(10) and R4(4)(24) rings in 1-deoxy-1-morpholino-D-fructopyranose

Acta Crystallogr C. 2007 Sep;63(Pt 9):o507-9. doi: 10.1107/S0108270107034312. Epub 2007 Aug 9.

Abstract

In the title compound, C(10)H(19)NO(6), both rings adopt almost perfect chair conformations and their mutual orientation is influenced by an intramolecular O-H...N hydrogen bond. The molecules are linked by three independent O-H...O hydrogen bonds into sheets containing equal numbers of R2(2)(10) and R4(4)(24) rings.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbohydrate Conformation
  • Crystallography, X-Ray
  • Fructose / analogs & derivatives*
  • Fructose / chemistry*
  • Hydrogen Bonding
  • Models, Molecular
  • Molecular Conformation
  • Morpholines / chemistry*

Substances

  • Morpholines
  • Fructose
  • 1-deoxy-1-morpholinofructose