A simple method to determine kinetic deuterium isotope effects provides evidence that proton transfer to carbon proceeds over and not through the reaction barrier
J Am Chem Soc
.
2007 Aug 29;129(34):10330-1.
doi: 10.1021/ja073679g.
Epub 2007 Aug 4.
Authors
Wing-Yin Tsang
1
,
John P Richard
Affiliation
1
Department of Chemistry, University at Buffalo, Buffalo, New York 14260, USA.
PMID:
17676848
PMCID:
PMC2543129
DOI:
10.1021/ja073679g
No abstract available
Publication types
Research Support, N.I.H., Extramural
MeSH terms
Carbon / chemistry*
Deuterium
Kinetics
Molecular Structure
Protons*
Substances
Protons
Carbon
Deuterium
Grants and funding
R01 GM039754-20/GM/NIGMS NIH HHS/United States
R01 GM039754-19/GM/NIGMS NIH HHS/United States
GM 39754/GM/NIGMS NIH HHS/United States
R01 GM039754/GM/NIGMS NIH HHS/United States
R01 GM039754-21/GM/NIGMS NIH HHS/United States