Oxidation and mineralisation of substituted phenols by Fenton's reagent and catalytic wet oxidation

Water Sci Technol. 2007;55(12):37-45. doi: 10.2166/wst.2007.375.

Abstract

Catalytic abatement of solutions of 1,000 mg/L in phenol, ortho and para nitrophenol and ortho and para cresols was acomplished by using two catalytic systems. Fenton's reagent was used at 50 degrees C by adding 10 mg/L of ferrous cation and different dosages of H2O2. The mixture was reacting isothermically in a batch way during 3 hours. Catalytic wet oxidation (CWO) was carried out by using a commercial Activated Carbon, Industrial React FE01606A, CWO runs were carried out in a fixed bed reactor (FBR) with concurrent upflow. Temperature and oxygen pressure of the reactor were set to 160 degrees C and 16 bar, respectively. While phenols are quicky oxidised by the Fenton reagent higher mineralisation was obtained in the CWO process.

MeSH terms

  • Catalysis
  • Hydrogen Peroxide / chemistry*
  • Iron / chemistry*
  • Minerals / chemistry*
  • Oxidation-Reduction
  • Phenol / chemistry*
  • Phenol / toxicity
  • Water Pollutants, Chemical / chemistry
  • Water Pollutants, Chemical / toxicity

Substances

  • Fenton's reagent
  • Minerals
  • Water Pollutants, Chemical
  • Phenol
  • Hydrogen Peroxide
  • Iron