Organoruthenium derivative of the cyclic [H7P8W48O184]33- anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27-

Sib Sankar Mal; Nadeen H Nsouli; Michael H Dickman; Ulrich Kortz

doi:10.1039/b706762n

Organoruthenium derivative of the cyclic [H7P8W48O184]33- anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27-

Dalton Trans. 2007 Jul 7:(25):2627-30. doi: 10.1039/b706762n. Epub 2007 May 21.

Authors

Sib Sankar Mal¹, Nadeen H Nsouli, Michael H Dickman, Ulrich Kortz

Affiliation

¹ Jacobs University Bremen, School of Engineering and Science, 28725 Bremen, Germany.

PMID: 17576486
DOI: 10.1039/b706762n

Abstract

Reaction of [Ru(p-cymene)Cl2]2 with [H7P8W48O184]33- (P8W48) in aqueous acidic medium results in the organometallic derivative [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Molecular Conformation
Organometallic Compounds / chemistry*
Ruthenium / chemistry*
Tungsten / chemistry*

Substances

Organometallic Compounds
Ruthenium
Tungsten