Type-I phase matching for second-harmonic generation at 10.6 microm in LiGaTe(2) is demonstrated by using a tunable single-frequency continuous-wave CO(2) laser, and the nonlinear coefficient of LiGaTe(2) is determined from comparison with AgGaSe(2). The effective nonlinearity of LiGaTe(2) for this process amounts to 34.5 pm/V.