Synthesis of oxime phosphoranes from reaction between triphenylphosphine and acetylenic esters in the presence of oxime derivatives

Malek Taher Maghsoodlou; Sayyed Mostafa Habibi-Khorassani; Reza Heydari; Asadollah Hassankhani; Ghasem Marandi; Mahmoud Nassiri; Elaheh Mosaddeg

doi:10.1007/s11030-007-9062-8

Synthesis of oxime phosphoranes from reaction between triphenylphosphine and acetylenic esters in the presence of oxime derivatives

Mol Divers. 2007 May;11(2):87-91. doi: 10.1007/s11030-007-9062-8. Epub 2007 Jun 13.

Authors

Malek Taher Maghsoodlou¹, Sayyed Mostafa Habibi-Khorassani, Reza Heydari, Asadollah Hassankhani, Ghasem Marandi, Mahmoud Nassiri, Elaheh Mosaddeg

Affiliation

¹ Department of Chemistry, University of Sistan and Balouchestan, 98135-674, Zahedan, Iran. MT_maghsoodlou@yahoo.com

PMID: 17564809
DOI: 10.1007/s11030-007-9062-8

Abstract

A new one-pot, simple and effective procedure is presented for the preparation of O-containing phosphorus ylides by the Michael addition reaction of N-methylpyrrole-2-carbaldehydoxime, pyridin-2-carbaldehydoxime or acetophenonoxime with acetylenic esters.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkynes / metabolism*
Esters / metabolism
Models, Biological
Organophosphorus Compounds / metabolism*
Oximes / chemical synthesis*
Oximes / chemistry
Phosphoranes / chemical synthesis*
Phosphoranes / chemistry

Substances

Alkynes
Esters
Organophosphorus Compounds
Oximes
Phosphoranes
triphenylphosphine