Abstract
The reaction of DL-1,3-butadiene diepoxide and of DL-1,4-dibromo-2,3-butanediol with aqueous alkaline sodium arsenite, "Na(3)AsO(3)", gave mixtures of the title arsonic acids which can be separated by anion exchange resin. Characterization of by-products leads to a better understanding of these reactions. These compounds are valuable intermediates for the preparation of novel arsonic acids and bis(arsonic acids).
MeSH terms
-
Arsenicals / chemical synthesis
-
Arsenicals / chemistry*
-
Arsenites / chemistry
-
Butylene Glycols / chemistry*
-
Ion Exchange Resins
-
Lipids / chemistry*
-
Models, Chemical
-
Sodium Compounds / chemistry
-
Stereoisomerism
-
Water / chemistry
Substances
-
2,3,4-trihydroxybutylarsonic acid
-
2,3-dihydroxybutane-1,4-bis(arsonic acid)
-
Arsenicals
-
Arsenites
-
Butylene Glycols
-
Ion Exchange Resins
-
Lipids
-
Sodium Compounds
-
Water
-
sodium arsenite