A novel two-dimensional layered framework built of strontium(II) with 4-nitrobenzene-1,3-dicarboxylic acid

Acta Crystallogr C. 2007 Jun;63(Pt 6):m246-8. doi: 10.1107/S0108270107020100. Epub 2007 May 11.

Abstract

In poly[[aquastrontium(II)]-micro(6)-4-nitrobenzene-1,3-dicarboxylato-kappa(7)O(1):O(2):O(2):O(3):O(3),O(4):O(4)], [Sr(C(8)H(3)NO(6))(H(2)O)](n), the Sr(II) ion displays a distorted bicapped triangular prismatic configuration, defined by seven carboxyl O atoms from six symmetry-related ligands and one water molecule. The ligand molecules connect the Sr(II) ions into a two-dimensional layered framework in the ac plane, with close O...O contacts between the nitro groups and with each nitro group providing one acceptor O atom for a weak intermolecular C-H...O hydrogen bond.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography
  • Molecular Conformation
  • Organometallic Compounds / chemistry*
  • Strontium / chemistry*

Substances

  • Organometallic Compounds
  • Strontium