Abstract
Reaction of 1,19-di-unsubstituted b-bilene salts with alpha-ketoesters gives isoporphyrins, and eventually porphyrins, by way of an a,c-biladiene salt intermediate.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Catalysis
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Esters / chemistry
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Ketones / chemistry
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Models, Chemical
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Molecular Structure
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Porphyrins / chemical synthesis*
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Porphyrins / chemistry
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Stereoisomerism
Substances
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Esters
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Ketones
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Porphyrins
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b-Bilene
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biladiene A
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biladiene C