(Z)-2-[(1-Phenylsulfonyl-1H-indol-3-yl)methylene]-1-azabicyclo[2.2.2]octan-3-one semicarbazone

Acta Crystallogr C. 2007 May;63(Pt 5):o277-9. doi: 10.1107/S0108270107006129. Epub 2007 Apr 14.

Abstract

In crystals of the title compound, C(23)H(23)N(5)O(3)S, the indole system is planar and the phenyl ring of the phenylsulfonyl group makes a dihedral angle with the best plane of the indole system of 77.18 (4) degrees. The olefinic bond connecting the azabicyclic and indole systems has Z geometry. The geometry adopted by the C=O bond with respect to the N-N bond is trans. The O atom of the carbonyl group of each molecule is hydrogen bonded to the hydrazidic H atom of an adjacent molecule to form an eight-membered-ring dimeric structure.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Bridged Bicyclo Compounds, Heterocyclic / chemistry*
  • Crystallography, X-Ray
  • Indoles / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Molecular Structure
  • Radiation-Sensitizing Agents / chemistry*
  • Semicarbazones / chemistry

Substances

  • Bridged Bicyclo Compounds, Heterocyclic
  • Indoles
  • Radiation-Sensitizing Agents
  • Semicarbazones