Highly selective thiiranation of 1,2-allenyl sulfones with Br2 and Na2S2O3: mechanism and asymmetric synthesis of alkylidenethiiranes

Angew Chem Int Ed Engl. 2007;46(23):4379-81. doi: 10.1002/anie.200700619.

Authors

Chao Zhou¹, Chunling Fu, Shengming Ma

Affiliation

¹ Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou, 310027, Zhejiang, PR China.

PMID: 17476641
DOI: 10.1002/anie.200700619

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Bromine / chemistry*
Crystallography, X-Ray
Models, Molecular
Molecular Structure
Sulfhydryl Compounds / chemical synthesis*
Sulfhydryl Compounds / chemistry
Sulfones / chemistry*
Thiosulfates / chemistry*

Substances

Sulfhydryl Compounds
Sulfones
Thiosulfates
sodium thiosulfate
Bromine