Abstract
Novel transition metal catalysts based on oligonucleotides can be easily obtained by functionalization of 5-iodouridine with phosphine ligands, resulting in good asymmetric induction in palladium catalyzed allylic nucleophilic substitution.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Catalysis
-
Crystallography
-
DNA, Catalytic / chemical synthesis*
-
DNA, Catalytic / chemistry
-
Idoxuridine / analogs & derivatives*
-
Idoxuridine / chemistry
-
Ligands
-
Oligonucleotides / chemical synthesis*
-
Oligonucleotides / chemistry
-
Palladium / chemistry*
-
Phosphines / analysis*
-
Transition Elements / chemistry
Substances
-
DNA, Catalytic
-
Ligands
-
Oligonucleotides
-
Phosphines
-
Transition Elements
-
5-iodouridine
-
Palladium
-
phosphine
-
Idoxuridine