Abstract
The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chiral arene itself.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene Derivatives / chemistry*
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Electrons
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Lasers
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Mass Spectrometry / instrumentation
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Mass Spectrometry / methods*
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Models, Chemical
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Noble Gases / chemistry*
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Spectrum Analysis / instrumentation
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Spectrum Analysis / methods*
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Stereoisomerism
Substances
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Benzene Derivatives
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Noble Gases