Through-space R3-HETCOR experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR

J Magn Reson. 2007 Jun;186(2):220-7. doi: 10.1016/j.jmr.2007.02.015. Epub 2007 Mar 3.

Abstract

We present several new methods that allow to obtain through-space 2D HETCOR spectra between spin-1/2 and half-integer quadrupolar nuclei in the solid state. These methods use the rotary-resonance concept to create hetero-nuclear coherences through the dipolar interaction instead of scalar coupling into the HMQC and refocused INEPT experiments for spin n/2 (n>1). In opposite to those based on the cross-polarization transfer to quadrupolar nuclei, the methods are very robust and easy to set-up.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum Compounds / chemistry
  • Magnetic Resonance Spectroscopy / methods*
  • Phosphates / chemistry
  • Rotation
  • Sodium / chemistry

Substances

  • Aluminum Compounds
  • Phosphates
  • Sodium
  • aluminum phosphate