Abstract
The first, enantiocontrolled total synthesis of (+)-sundiversifolide has been accomplished using the sequential ring-closing metathesis, [3,3]-sigmatropic rearrangement, and iodolactonization for the key assembly of the cis-fused oxabicyclo[5.3.0]decene framework of the natural product. [structure: see text]
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Biological Products / chemical synthesis*
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Bridged Bicyclo Compounds / chemistry
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Bridged-Ring Compounds / chemistry
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Cyclization
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Lactones / chemistry
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Models, Chemical
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Stereoisomerism
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Xanthenes / chemical synthesis*
Substances
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Biological Products
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Bridged Bicyclo Compounds
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Bridged-Ring Compounds
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Lactones
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Xanthenes
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bicyclo(5.3.0)decane
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sundiversifolide