Solvent-free, heterogeneous photooxygenation of hydrocarbons by hyflon membranes embedding a fluorous-tagged decatungstate

Mauro Carraro; Martino Gardan; Gianfranco Scorrano; Enrico Drioli; Enrica Fontananova; Marcella Bonchio

doi:10.1039/b610551c

Solvent-free, heterogeneous photooxygenation of hydrocarbons by hyflon membranes embedding a fluorous-tagged decatungstate

Chem Commun (Camb). 2006 Nov 21:(43):4533-5. doi: 10.1039/b610551c.

Authors

Mauro Carraro¹, Martino Gardan, Gianfranco Scorrano, Enrico Drioli, Enrica Fontananova, Marcella Bonchio

Affiliation

¹ ITM-CNR and Department of Chemical Sciences, University of Padova, Via Marzolo, 1, 35131, Padova, Italy.

PMID: 17283809
DOI: 10.1039/b610551c

Abstract

Hybrid fluoropolymeric membranes with 25% loading of the fluorous-tagged (RfN)4W10O32 effect the solvent-free photooxygenation of benzylic C-H bonds with up to 6100 TONs in 4 hours.