Dioxin concentrations in sediments of the Baltic Sea--a survey of existing data

Chemosphere. 2007 Apr;67(9):1762-75. doi: 10.1016/j.chemosphere.2006.05.125. Epub 2007 Jan 16.

Abstract

Recent survey results for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs, dioxins) in Baltic Sea sediments from Finland, Sweden and Denmark were merged with previously published Baltic Sea data. Regional distribution of concentration levels, differences in congener patterns, and temporal changes in sediment profiles were examined. One of the main objectives was to study if any major point sources for different PCDD/F congeners could be identified on a regional scale, based on sediment records. The survey confirmed the impact of chlorophenol production derived highly chlorinated PCDF-congeners on the total toxicity in sediments in the Gulf of Finland near the Kymijoki river estuary. Signatures of other point sources or combined point sources pertinent to specific industry branches or particular production processes (such as pulp bleaching, vinyl chloride production, thermal processes) may be discerned. However, the findings did not support any of the known point sources significantly influencing those congeners that are most abundant in Baltic herring and salmon. Instead, regional distributions in the Baltic Sea indicate that atmospheric deposition may act as a major source for those congeners and especially for 2,3,4,7,8-PeCDF. There were clear indications of declines in levels in sediment in some areas, but generally the levels of highly chlorinated PCDD/Fs on the northern coast of the Gulf of Finland were still high when compared with other areas of the Baltic Sea. Major areas with data gaps cover the south-eastern and eastern coastal regions of the Baltic Proper and the southern Gulf of Finland.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzofurans / analysis
  • Data Collection
  • Denmark
  • Dioxins / analysis*
  • Environmental Monitoring*
  • Finland
  • Fresh Water / chemistry
  • Geography
  • Geologic Sediments / analysis*
  • Geologic Sediments / chemistry
  • Industrial Waste
  • Oceans and Seas
  • Polychlorinated Dibenzodioxins / analogs & derivatives
  • Polychlorinated Dibenzodioxins / analysis
  • Soil Pollutants / analysis*
  • Sweden
  • Time Factors

Substances

  • Benzofurans
  • Dioxins
  • Industrial Waste
  • Polychlorinated Dibenzodioxins
  • Soil Pollutants