Spectral editing in solid-state MAS NMR of quadrupolar nuclei using selective satellite inversion

Krishna K Dey; S Prasad; Jason T Ash; Michael Deschamps; Philip J Grandinetti

doi:10.1016/j.jmr.2006.12.013

Spectral editing in solid-state MAS NMR of quadrupolar nuclei using selective satellite inversion

J Magn Reson. 2007 Apr;185(2):326-30. doi: 10.1016/j.jmr.2006.12.013. Epub 2006 Dec 23.

Authors

Krishna K Dey¹, S Prasad, Jason T Ash, Michael Deschamps, Philip J Grandinetti

Affiliation

¹ Department of Chemistry, The Ohio State University, 120 W. 18th Avenue, Columbus, OH 43210-1173, USA.

PMID: 17218134
DOI: 10.1016/j.jmr.2006.12.013

Abstract

A sensitivity enhancement method based on selective adiabatic inversion of a satellite transition has been employed in a (pi/2)CT-(pi)ST1-(pi/2)CT spectral editing sequence to both enhance and resolve multisite NMR spectra of quadrupolar nuclei. In addition to a total enhancement of 2.5 times for spin 3/2 nuclei, enhancements up to 2.0 times is reported for the edited sites in a mixture of rubidium salts.

Publication types

Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Algorithms*
Computer Simulation
Magnetic Resonance Spectroscopy / methods*
Models, Chemical*
Models, Molecular*
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