Reaction of arenes with iodine in the presence of potassium peroxodisulfate in trifluoroacetic acid. Direct and simple synthesis of diaryliodonium triflates

Md Delwar Hossain; Yasuyuki Ikegami; Tsugio Kitamura

doi:10.1021/jo061889q

Reaction of arenes with iodine in the presence of potassium peroxodisulfate in trifluoroacetic acid. Direct and simple synthesis of diaryliodonium triflates

J Org Chem. 2006 Dec 22;71(26):9903-5. doi: 10.1021/jo061889q.

Authors

Md Delwar Hossain¹, Yasuyuki Ikegami, Tsugio Kitamura

Affiliation

¹ Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan.

PMID: 17168620
DOI: 10.1021/jo061889q

Abstract

Diaryliodonium triflates have been directly prepared by reaction of arenes with elemental iodine in good yields by using K2S2O8 and TFA, followed by treatment with NaOTf. This procedure avoids the use of high temperature and severe reaction conditions.

MeSH terms

Benzene Derivatives / chemistry*
Hydrocarbons, Iodinated / chemical synthesis*
Hydrocarbons, Iodinated / chemistry
Iodine / chemistry*
Potassium Compounds / chemistry*
Sulfates / chemistry*
Trifluoroacetic Acid / chemistry*

Substances

Benzene Derivatives
Hydrocarbons, Iodinated
Potassium Compounds
Sulfates
potassium persulfate
Iodine
Trifluoroacetic Acid