Abstract
A new Mn(Salen) complex bearing an ureido group as an auxiliary that is three-dimensionally fixed by a cyclopentane ring fused to the Salen structure was developed. This compound exhibited considerably higher catalase-like activity than the original Mn(Salen), i.e., the cyclopentane-fused Mn(Salen) without the auxiliary, under near-physiological conditions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Crystallography, X-Ray
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Cyclopentanes / chemistry
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Enzyme Activation
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Ethylenediamines / chemical synthesis
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Ethylenediamines / chemistry*
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Hydrogen Bonding
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Hydrogen Peroxide / chemistry
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Ligands
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Stereoisomerism
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Time Factors
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Urea / chemistry
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Water / chemistry
Substances
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Cyclopentanes
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Ethylenediamines
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Ligands
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Organometallic Compounds
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Water
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N,N'-bis(salicylideneamino)ethane-manganese(II)
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Urea
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Hydrogen Peroxide