[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2- and pyrazine ligands

Jamie L Manson; Marianne M Conner; John A Schlueter; Tom Lancaster; Stephen J Blundell; Michael L Brooks; Francis L Pratt; Thomas Papageorgiou; Andreas D Bianchi; Jochen Wosnitza; Myung-Hwan Whangbo

doi:10.1039/b608791d

[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2- and pyrazine ligands

Chem Commun (Camb). 2006 Dec 21:(47):4894-6. doi: 10.1039/b608791d. Epub 2006 Aug 22.

Authors

Jamie L Manson¹, Marianne M Conner, John A Schlueter, Tom Lancaster, Stephen J Blundell, Michael L Brooks, Francis L Pratt, Thomas Papageorgiou, Andreas D Bianchi, Jochen Wosnitza, Myung-Hwan Whangbo

Affiliation

¹ Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu

PMID: 17136238
DOI: 10.1039/b608791d

Abstract

[Cu(HF2)(pyz)2]BF4 consists of rare mu(1,3) bridging HF2- anions and micro-pyrazine ligands leading to a 3D pseudo-cubic framework that antiferromagnetically orders below 1.54(1) K.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Copper / chemistry*
Crystallography, X-Ray
Hydrofluoric Acid / chemistry*
Ligands
Magnetics
Models, Molecular
Organometallic Compounds / chemistry*
Polymers / chemistry*
Pyrazines / chemistry*
Stereoisomerism
Temperature

Substances

Ligands
Organometallic Compounds
Polymers
Pyrazines
Copper
Hydrofluoric Acid