Abstract
The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of alpha,beta-unsaturated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh2(pfb)4, proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aldehydes / chemistry*
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Catalysis
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Fluorocarbons / chemistry*
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Ketones / chemistry*
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Molecular Structure
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Organometallic Compounds / chemistry*
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Rhodium / chemistry*
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Silanes / chemical synthesis*
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Silanes / chemistry
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Stereoisomerism
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Vinyl Compounds / chemical synthesis*
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Vinyl Compounds / chemistry
Substances
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Aldehydes
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Fluorocarbons
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Ketones
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Organometallic Compounds
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Silanes
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Vinyl Compounds
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vinyl ether
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Rhodium