Abstract
This report presents the first simultaneous, metal-free synthesis of block copolymers through combination of enzymatic ring-opening polymerisation of epsilon-caprolactone with RAFT-mediated controlled radical polymerisation of styrene.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Candida / enzymology
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Caproates / chemistry
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Carbon Monoxide / chemistry*
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Ethanol / chemistry*
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Fungal Proteins
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Lactones / chemistry
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Lipase / metabolism*
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Molecular Structure
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Nitriles / chemistry
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Nitriles / metabolism
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Polymers / chemistry*
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Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
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Styrene / chemistry
Substances
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Caproates
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Fungal Proteins
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Lactones
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Nitriles
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Polymers
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Ethanol
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Styrene
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caprolactone
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Carbon Monoxide
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Lipase
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lipase B, Candida antarctica
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azobis(isobutyronitrile)