In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS

Gemma Guilera; Mark A Newton; Charlene Polli; Sakura Pascarelli; Meritxell Guinó; King Kuok Hii

doi:10.1039/b606772g

In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS

Chem Commun (Camb). 2006 Nov 4:(41):4306-8. doi: 10.1039/b606772g. Epub 2006 Sep 4.

Authors

Gemma Guilera¹, Mark A Newton, Charlene Polli, Sakura Pascarelli, Meritxell Guinó, King Kuok Hii

Affiliation

¹ European Synchrotron Radiation Facility (ESRF, ID24), PO Box 220, 38043 Grenoble Cedex, France. guilera@esrf.fr

PMID: 17047849
DOI: 10.1039/b606772g

Abstract

Simultaneous structuro-kinetic information obtained via time resolved stopped-flow/UV-Vis spectroscopy/dispersive EXAFS (EDE) experiments elucidated a two-step process for the addition of iodobenzene to [(Ph3P)2Pd(dba)].