Self-assembly of square-planar halide complexes of phosphine-stabilised stibenium salts

J Wolfram Wielandt; Nathan L Kilah; Anthony C Willis; S Bruce Wild

doi:10.1039/b607136h

Self-assembly of square-planar halide complexes of phosphine-stabilised stibenium salts

Chem Commun (Camb). 2006 Sep 21:(35):3679-80. doi: 10.1039/b607136h. Epub 2006 Jul 5.

Authors

J Wolfram Wielandt¹, Nathan L Kilah, Anthony C Willis, S Bruce Wild

Affiliation

¹ Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200, Australia.

PMID: 17047809
DOI: 10.1039/b607136h

Abstract

Chloride and bromide ions direct the self-assembly of supramolecular square-planar halide complexes in which four trimethylphosphine-stabilised diphenylstibenium ions surround the central halide ion in discrete centrosymmetrical structures of C(4h) symmetry.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Antimony / chemistry*
Bromides / chemistry*
Chlorides / chemistry*
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Conformation
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry
Phosphines / chemistry*
Sensitivity and Specificity
Stereoisomerism

Substances

Bromides
Chlorides
Organometallic Compounds
Phosphines
Antimony
phosphine