Survey of catalysts for oxidation of mercury in flue gas

Environ Sci Technol. 2006 Sep 15;40(18):5601-9. doi: 10.1021/es060504i.

Abstract

Methods for removing mercury from flue gas have received increased attention because of recent limitations placed on mercury emissions from coal-fired utility boilers by the U. S. Environmental Protection Agency and various states. A promising method for mercury removal is catalytic oxidation of elemental mercury (Hg0) to oxidized mercury (Hg2+), followed by wet flue gas desulfurization (FGD). FGD cannot remove Hg0, but easily removes Hg2+ because of its solubility in water. To date, research has focused on three broad catalyst areas: selective catalytic reduction catalysts, carbon-based materials, and metals and metal oxides. We review published results for each type of catalyst and also present a discussion on the possible reaction mechanisms in each case. One of the major sources of uncertainty in understanding catalytic mercury oxidation is a lack of knowledge of the reaction mechanisms and kinetics. Thus, we propose that future research in this area should focus on two major aspects: determining the reaction mechanism and kinetics and searching for more cost-effective catalyst and support materials.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.
  • Review

MeSH terms

  • Air Pollutants / chemistry*
  • Air Pollutants / isolation & purification
  • Air Pollution / prevention & control
  • Catalysis
  • Coal*
  • Gases / chemistry
  • Mercury / chemistry*
  • Mercury / isolation & purification
  • Metals / chemistry
  • Oxidation-Reduction
  • Oxides / chemistry

Substances

  • Air Pollutants
  • Coal
  • Gases
  • Metals
  • Oxides
  • Mercury