Ketosteroids and hydroxyketosteroids, minor metabolites of sugarcane wax

Steroids. 2006 Aug;71(8):647-52. doi: 10.1016/j.steroids.2006.01.016. Epub 2006 Jun 23.

Abstract

Besides beta-sitosterol and stigmasterol, the major steroids of sugarcane, the following minor steroids have been isolated and identified from sugarcane wax: 3,6-diketosteroids, Delta(4)-3-keto steroids, and Delta(4)-6-hydroxy-3-keto steroids. Their structures were established by spectroscopic techniques and chemical correlations.

MeSH terms

  • Gas Chromatography-Mass Spectrometry
  • Hydroxysteroids / chemistry
  • Hydroxysteroids / isolation & purification
  • Hydroxysteroids / metabolism*
  • Ketosteroids / chemistry
  • Ketosteroids / isolation & purification
  • Ketosteroids / metabolism*
  • Magnetic Resonance Spectroscopy
  • Models, Biological
  • Plant Structures / chemistry
  • Plant Structures / metabolism
  • Saccharum / chemistry
  • Saccharum / metabolism*
  • Sitosterols / analysis
  • Sitosterols / isolation & purification
  • Stigmasterol / analysis
  • Stigmasterol / isolation & purification
  • Waxes / chemistry
  • Waxes / metabolism*

Substances

  • Hydroxysteroids
  • Ketosteroids
  • Sitosterols
  • Waxes
  • gamma-sitosterol
  • Stigmasterol