Abstract
A new alkyne-containing chelating ligand, 1,2-di(quinolin-8-yl)ethyne, is shown to form a mononuclear 1:1 complex with silver(I) and chelate the metal ion through both nitrogens and the ethyne moiety as seen by UV and NMR spectroscopy as well as X-ray crystallography.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Acetylene / analogs & derivatives*
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Acetylene / chemical synthesis
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Acetylene / chemistry
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Alkynes / chemical synthesis
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Alkynes / chemistry
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Chelating Agents / chemical synthesis
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Chelating Agents / chemistry*
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Crystallography, X-Ray
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Magnetic Resonance Spectroscopy
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Molecular Conformation
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Molecular Structure
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Quinolines / chemical synthesis
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Quinolines / chemistry*
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Silver / chemistry*
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Solvents / chemistry
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Spectrophotometry, Ultraviolet
Substances
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Alkynes
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Chelating Agents
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Quinolines
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Solvents
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Silver
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Acetylene